[UHH] [FB13] [LCI]
[LC] [SD] [LB]

LiqCryst Compound LC 43981

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    Compound description:

    LC Reg. Number:43981
    Molecular formula:C34H50O2
    Mol mass:490.76 g/mol
    Cholesteryl benzoate


    PTCr 150.5 N* 182.6 isMCLC 12,367
    PTCr 146.6 N* 180.6 isMC 1,309
    PTCr 154.4 N* 179.9 is(112)
    PTCr 145.8 N* 180.7 isMCLC 18,195
    PTCr 147 N* 186 isMCLC 15,105
    PTCr 148 N* 176 isMCLC 80,179
    PTTm2 ? , Tm3 ?(1370)
    PTCr 151 X 178.5 is(1370)
    PTCr2 136.8 Cr1 145.7 N* 184.7 isMCLC 88,137
    PTCr 129 N* 118 isMCLC 100,49
    PTCr 145.5 X 178.5 is(2054)
    PTpressure dep.(2067)
    PTCr 150 N* 182 is(2436)
    PTCr 149 N* 178.0 is(2470)
    PTsolid state polymorphismMCLC 128,367
    PTCr 151 N* 180 is,solv.f.react.(2692)
    PTCr 145 N* 178 is(2740)
    PTCr 145.5 N* 178.6 is(2838)
    PTCr 145.5 X 178.5 is(2873)
    PTCr 150 N* 178 is(2915)
    PT(130) Cr 156 X 186 un(3007)
    PTCr 145 N* 178 is(3410)
    PTCr 150 N* 178 is(3537)
    PTCr 147 N* 176 is(4504)
    PT6 solid phases(4972)
    PTCr ? N* 182.5 BP 182.8 is(7552)
    PTCr 150 N* 178.5 is(7711)
    PTCr 147.0 N* 179.5 is(9143)
    PTCr 147.0 N* 173.9 is(9895)
    PTCr 117 N* 160 is(11091)
    PTCr 149 N* 179 un(13120)
    PTCr 149 N* 179 is(13633)
    PTC#, A# in mix.MCLC 260,377
    PTA#, C# in mix.SPIE 3318,90
    PTCr 149 N* 178 is(18235)
    PTCr 148 N* 176 is(18377)
    PTinduced A, C*, B in mix.MCLC 330,483
    PTCr 148 N* 176 isJCP 76,866
    PTN* in mix(22663)
    ThermoΔH(N*-is) 0.16 kcal/mol, T = 182.6 °CMCLC 12,367
    ThermoΔH(Cr-N*) 7.82 kcal/mol, T = 150.5 °CMCLC 12,367
    ThermoΔH(N*-is) 0.124 kcal/mol, T = 179.9 °C(112)
    ThermoΔH(N*-is) 0.17 kcal/mol, T = 180.7 °CMCLC 18,195
    ThermoΔH(Cr-N*) 5.30 kcal/mol, T = 145.8 °CMCLC 18,195
    ThermoΔH(Cr-Cr) 5.94 kJ/mol, T = 136.8 °CMCLC 88,137
    ThermoΔH(Cr-N*) 22.13 kJ/mol, T = 145.7 °CMCLC 88,137
    ThermoΔH(N*-is) 0.63 kJ/mol, T = 184.7 °CMCLC 88,137
    ThermoΔH(N*-is) 0.151 kcal/mol, T = 180.8 °CCL 1980,471
    ThermoΔH(Cr-N*) 5.29 kcal/mol, T = 146.1 °CCL 1980,471
    ThermoΔH(N*-is) 0.17 kcal/mol, T = 178 °C(12739)
    ThermoΔH(Cr-N*) 5.30 kcal/mol, T = 146 °C(12739)
    Densityρ(T)MCLC 80,179
    Opticsn(T)MCLC 80,179
    Opticsn(T) simplified(9929)
    Opticsα|| 89.282 E-24 cm3MCLC 80,179
    Opticsα┴ 40.759 E-24 cm3MCLC 80,179
    OpticsΔα 48.523 E-24 cm3MCLC 80,179
    Opticsoptical rotation(3425)
    OrderS(T)JCP 76,866
    Viscosityη(T) (bulk)(2056)
    Viscosityη(T)JPSJ 28,470
    X-Raydiff.MCLC 15,105
    X-RaystructureMCLC 128,367
    X-Raycrystal data(4052)
    X-Raycrystal data(4772)
    X-Raycrystal data(17132)
    Spectra1H-NMRMCLC 100,49
    Spectra1H-NMR T1 = 0.15s, T = ? °CJCP 27,1081
    Spectra1H-NMR T2(1)=30ms T2(0.1)=20ms, T = ? °CJCP 27,1081
    Spectra1H-NMR line width(T)(3827)
    Spectra1H-NMRJCP 76,866
    Spectra1H-NMR in BPJCP 76,1209
    SpectraIRMCLC 76,133
    SpectraIRMCLC 98,175
    SpectraIR steric structure(2471)
    Numerical Tabledensity ρ(T)MCLC 80,179
    Numerical Tabledensity ρ(T)(2055)
    Numerical TableRI ne|no(T) (546.1 nm)MCLC 80,179
    Numerical TableRI ne|no(T) (589.3 nm)MCLC 80,179
    Numerical TableRI ne|no(T)(4071)
    Numerical Tablesurface tension σ(T)(2055)
    Numerical Tabledynamic viscosity η(T)(2056)
    Numerical Tabledynamic viscosity η(T)JPSJ 28,470
    Numerical Tablesound velocity v(T)JCP 24,803
    Numerical Tablesound velocity v(T)(9144)
    Numerical Tablesound velocity v(T)(9909)
           IDACC API-01933ACC
           PNCholesteryl Benzoate, >95%ACC
           Size25 gACC
           Size100 gACC
           IDAcros 11020 0250 
           PNCholesterylbenzoat, 98% 
           PNCholesteryl benzoate, 98% 
           Size25 GR 
           IDAldrich C7,580-2 
           PNCholesteryl benzoate 
           IDAppliChem A0809,0010 
           PNCholesterylbenzoat BioChemica 
           PNCholesteryl benzoate BioChemica 
           Size10 g 
           IDAppliChem A0809,0025 
           PNCholesterylbenzoat BioChemica 
           PNCholesteryl benzoate BioChemica 
           Size25 g 
           IDChangChem CC-134 
           PNCholesteryl benzoate 
           IDChemos C0320 
           PNCholesteryl benzoate 
           IDFluka 26760 
           PNCholesteryl benzoate 
           IDFluka 26760 
           PNCholesteryl benzoate, purum, >=97.0% (HPLC) 
           IDFluka 78886 
           PNCetrimide Broth, BioChemika, for microbiology 
           IDFrinton FR-0276 
           PNCholesteryl Benzoate 
           PNCholesteryl BenzoateHarteg
           IDICN 104774 
           PNCholesteryl benzoate 
           IDLancaster 3590 
           CompanyLancaster Synthesis GmbH 
           SourceLancaster Katalog 2003 
           PNCholesteryl benzoate 98% 
           IDMP 104774 
           PNCholesteryl benzoate 
           IDPressChem L010PressChem
           IDRoth 3402 
           CompanyCarl Roth GmbH 
           SourceChemikalienkatalog 2002/2003 
           PNCholesteryl-benzoat, >98%, krist. 
           SizeRoth 3402.1 CHOLESTERYL-BENZOAT 10G 
           IDSigma C8878 
           PNCholesteryl benzoate 
           IDTCI C0320 
           PNCholesterol benzoate 
    Dataμ 2.40 D(2738)
    Dataμ 1.90 D (calc.)(3560)
    Dataμ 1.62 D (C6H6), T = 45 °C(5396)
    Dataμ 2.08 D (CCl4)(9143)
    Dataμ 2.11 D (C6H6)(9143)
    DataEa(T)JPSJ 28,470
    Datap(T) in mixtures(3698)
    Dataβ(T) in HOABMCLC 40,133
    Dataβ(T) in PAA(3352)
    Dataβ(T) in PAA(3380)
    Dataβ -5.0 μm-1 (in 5CB)MCLC 64,211
    Datapositron annihilation lifetimeJCP 57,1597
    Datapositron lifetime(T)JCP 42,1692
    Dataultrasonic velocityJCP 24,803
    Dataultrasonic velocity(9144)
    Dataultrasonic velocity(9909)
    DataGC : stationary phase(4527)
    DataGC : stationary phase (mix)(22739)
    Datasurface tension(2055)
    Dataelectron diffraction(3567)
    Datadynamic mechanical behav. in KMCLC 103,299
    Datadopant C*(6149)
    Datadopant C*, Ch(7186)
    Datawetting of graphite(8569)
    Datasolvent asymmetric synthesis(18377)
    Dataname: Ch-1 (translated)(18896)
    Dataname: X-1 (russ.)(18896)
    Dataoptical prop. in mix.MC 1,293
    DataβM -9.9 μm-1 (in 5CB)MCLC 64,211
    Datacholesteric coating inks (mix)(20642)
    Datacholesteric mix., emulsion(20711)
    Datause for γ-ray dosimeter(22747)


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    Page: 1840-1845
    Year: 1992
    Title: Temperature and impurity concentration dependence of anomalously low light absorption in the mesophase of cholesteryl benzoate
    Author: Zagainova, L.I.; Klimusheva, G.V.; Kryzhanovskii, I.P.
    Source: Fiz. Tverd. Tela (Leningrad)
    Volume: 25
    Page: 1025-1029
    Year: 1983
    Title: Ordering and conformation transformations in cholesteryl benzoate
    Author: Golovina, N.A.; Zagainova, L.I.; Polishchuk, A.P.; Puchkovskaya, G.A.; Tatarinov, S.I.
    Source: Zh. Prikl. Spektrosk.
    Volume: 49
    Page: 833-839
    Year: 1988
    Title: Rapid detection and identification of liquid crystal states by light scattering
    Author: Santoro, A.; Esposito, M.
    Source: J. Therm. Anal.
    Volume: 6
    Page: 101-107
    Year: 1974
    Internet Resource: DOI: 10.1007/BF01911492
    Author: Bahadur, B.
    Source: Acustica
    Volume: 34
    Page: 86
    Year: 1975
    Title: Temperature changes of the refractive index of cholesteric liquid crystals
    Author: Kupka, Zdenek; Dvorak, Lubomir; Pospisil, Eduard
    Source: Acta Univ. Palacki. Olomuc., Fac. Rerum Nat.
    Volume: 53
    Page: 271-281
    Year: 1977
    Title: Product List
    Author: American Custom Chemicals Corporation
    Year: 2008
    Internet Resource: http://www.acccorporation.com/
    CL 1980,471
    Title: Mesomorphic properties of some cholesteryl arylbenzoates
    Author: Koden, M.; Takenaka, S.; Kusabayshi, S.
    Source: Chem. Lett.
    Volume: 9
    Page: 471-472
    Year: 1980
    Internet Resource: DOI:10.1246/cl.1980.471
    Author: HARTEG GmbH
    Year: 2007
    Internet Resource: http://www.harteg.com/
    Address: Bärensteiner Str.13
    Address: 01277 Dresden
    Address: Germany
    Address: Tel/Fax Central: +49 (0) 351 6465219
    JCP 24,803
    Author: Hoyer, W.A.; Nolle, A.W.
    Source: J. Chem. Phys.
    Volume: 24
    Page: 803-811
    Year: 1956
    JCP 27,1081
    Author: Runyan, W.R.; Nolle, A.W.
    Source: J. Chem. Phys.
    Volume: 27
    Page: 1081
    Year: 1957
    JCP 42,1692
    Author: Cole, G.D.; Walker, W.W.
    Source: J. Chem. Phys.
    Volume: 42
    Page: 1692
    Year: 1965
    JCP 57,1597
    Title: Phase and temperature dependence of positron annihilation in liquid crystals
    Author: Nicholas, I.B.; Ache, H.J.
    Source: J. Chem. Phys.
    Volume: 57
    Page: 1597-1603
    Year: 1972
    JCP 76,1209
    Title: Nuclear magnetic resonance spectroscopy in cholesteric liquid crystals. II. The blue phase
    Author: Shivaprakash, N.C.; Shashidhara Prasad, J.
    Source: J. Chem. Phys.
    Volume: 76
    Page: 1209-1211
    Year: 1982
    JCP 76,866
    Title: Nuclear magnetic resonance spectroscopy in cholesteric liquid crystals. I. Orientational order parameter measurements
    Author: Shivaprakash, N.C.; Shashidhara Prasad, J.
    Source: J. Chem. Phys.
    Volume: 76
    Page: 866-871
    Year: 1982
    JPSJ 28,470
    Title: Viscous behavior of cholesteric liquid crystals
    Author: Kartha, C.G.; Agarwal, R.K.L.P.
    Source: J. Phys. Soc. Jpn.
    Volume: 28
    Page: 470-473
    Year: 1970
    Internet Resource: DOI: 10.1143/JPSJ.28470
    MC 1,293
    Title: Cholesteric structure. I. Optical properties
    Author: Fergason, J.L.
    Source: Mol. Cryst.
    Volume: 1
    Page: 293-307
    Year: 1966
    Internet Resource: DOI: 10.1080/15421406608083274
    MC 1,309
    Title: Cholesteric structure. II. Chemical significance
    Author: Fergason, J.L.; Goldberg, N.N.; Nadalin, R.J.
    Source: Mol. Cryst.
    Volume: 1
    Page: 309-323
    Year: 1966
    Internet Resource: DOI: 10.1080/15421406608083275
    MCLC 100,49
    Title: NMR study of the phase transitions in some derivatives of cholesterol and B-norcholesterol
    Author: Nicula, A.; Selinger, S.; Bogdan, M.; Todica, M.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 100
    Page: 49-55
    Year: 1983
    Internet Resource: DOI: 10.1080/00268948308073718
    MCLC 103,299
    Title: Dynamic mechanical behavior of some cholesteryl liquid crystals
    Author: Deshpande, D.D.; Tiwari, V.K.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 103
    Page: 299-305
    Year: 1983
    Internet Resource: DOI: 10.1080/00268948308071061
    MCLC 12,367
    Title: Mesomorphism of homologous series. II. Odd-even effect
    Author: Ennulat, R.D.; Brown, A.J.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 12
    Page: 367-378
    Year: 1971
    Internet Resource: DOI: 10.1080/15421407108082788
    MCLC 128,367
    Title: Solid state polymorphism of mesogenic cholesteryl benzoate
    Author: Polishchuk, A.P.; Kulishov, V.I.; Timofeeva, T.V.; Antipin, M.Y.; Struchkov, Yu.T.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 128
    Page: 367-385
    Year: 1985
    Internet Resource: DOI: 10.1080/00268948508082183
    MCLC 15,105
    Title: Polymorphic and mesomorphic behavior of four esters of cholesterol
    Author: Merritt, W.G.; Cole, G.D.; Walker, W.W.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 15
    Page: 105-120
    Year: 1971
    Internet Resource: DOI: 10.1080/15421407108083228
    MCLC 18,195
    Title: Order and flow in liquid crystals. XXIX. Effect of substituent location on the thermodynamic properties of cholesteryl halobenzoates and halocinnamates
    Author: Barrall, E.M.; Bredfeldt, K.E.; Vogel, M.J.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 18
    Page: 195-207
    Year: 1972
    Internet Resource: DOI: 10.1080/15421407208083594
    MCLC 260,377
    Title: Twist grain boundary phases in binary mixtures
    Author: Kuczynski, W.; Stegemeyer, H.
    Source: Mol. Cryst. Liq. Cryst. A
    Volume: 260
    Page: 377-386
    Year: 1995
    Internet Resource: DOI: 10.1080/10587259508038711
    MCLC 330,483
    Title: Induced chiral smectic phase in the mixture of cholesteric and nematic compounds
    Author: Raju, B.T.; Mahadeva, J.; Nagappa; Alapati, P.R.
    Source: Mol. Cryst. Liq. Cryst. A
    Volume: 330
    Page: 483-490
    Year: 1999
    Internet Resource: DOI: 10.1080/10587259908025625
    MCLC 40,133
    Title: Optical and x-ray studies on the twisted smectic C and twisted nematic phases. Evidence for a skew-cybotactic type of cholesteric structure
    Author: Suresh, K.A.; Chandrasekhar, S.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 40
    Page: 133-141
    Year: 1977
    Internet Resource: DOI: 10.1080/15421407708084476
    MCLC 64,211
    Title: Helical twisting powers of steroidal molecules in aromatic nematic liquid crystals
    Author: Hibert, M.; Solladie, G.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 64
    Page: 211-216
    Year: 1981
    Internet Resource: DOI: 10.1080/01406568108080167
    MCLC 76,133
    Title: Vibrational spectra of cholesteric liquid crystals
    Author: Shivaprakash, N.C.; Narasimhamurthy, B.; Prasad, J.S.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 76
    Page: 133-144
    Year: 1981
    Internet Resource: DOI: 10.1080/00268948108074681
    MCLC 80,179
    Title: Refractive indexes, densities, polarizabilities and molecular order in cholesteric liquid crystals
    Author: Shivaprakash, N.C.; Abdoh, M.M.M.; Srinivasa; Prasad, J.S.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 80
    Page: 179-183
    Year: 1982
    MCLC 88,137
    Title: Influence of the angular linkage on the mesomorphic properties of cholesteryl arylbenzoates
    Author: Koden, M.; Takenaka, S.; Kusabayashi, S.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 88
    Page: 137-150
    Year: 1982
    Internet Resource: DOI: 10.1080/00268948208072592
    MCLC 98,175
    Title: The effect of substituents at benzoic ring on the parameters of cholesteryl benzoates infrared spectra in phase transitions
    Author: Laskovets, A.D.; Gorina, I.I.; Gorbatenko, L.S.; Chistyakov, I.G.; Mikhailenko, G.V.
    Source: Mol. Cryst. Liq. Cryst.
    Volume: 98
    Page: 175-182
    Year: 1983
    Internet Resource: DOI: 10.1080/00268948308073472
    Title: Liquid Crystal Supplier
    Author: Pressure Chemical Company
    Year: 2008
    Internet Resource: http://www.presschem.com/
    Address: 3419 Smallman Street
    Address: Pittsburgh, PA 15201
    SPIE 3318,90
    Title: Polymorphism of twist grain boundary phases near the chiral NAC point
    Author: Kuczynski, W.; Stegemeyer, H.
    Source: Proc. SPIE-Int. Soc. Opt. Eng.
    Volume: 3318
    Page: 90-93
    Year: 1998

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